%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % the atomicreactions package % % Adds many symbols for using in scientific tex files. % Those symbols are used by some plotting tools etc. % % -------------------------------------------------------------------------- % B. Michel Döhring % -------------------------------------------------------------------------- % GitHub: https://github.com/micheld93/atomicreactions-LaTeX % CTAN: https://www.ctan.org/pkg/atomicreactions % -------------------------------------------------------------------------- % If you have any questions, bugs or suggestions to report, please % feel free to get in touch. %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % Copyright 2026 B. Michel Döhring % % This work may be distributed and/or modified under the % conditions of the LaTeX Project Public License, either version 1.3 % of this license or (at your option) any later version. % The latest version of this license is in % http://www.latex-project.org/lppl.txt % and version 1.3 or later is part of all distributions of LaTeX % version 2005/12/01 or later. % % This work has the LPPL maintenance status `maintained'. % % The Current Maintainer of this work is Michel Döhring. %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % The atomicreactions package consists of the following files % - atomicreactions.sty % - atomicreactions-manual.tex % - atomicreactions.bib % - atomicreactions-manual.pdf % - README.md %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% \RequirePackage{tikz} \usetikzlibrary{patterns} \usetikzlibrary{arrows} \RequirePackage{xparse} % package information: \ProvidesPackage{atomicreactions}[2026/05/01 atomic shell reactions] %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%% % Atomic physics reactions % %%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%% % % % % % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % Empty Reaction with center circle at 0/0 % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % Empty reaction picture \newcommand{\atomEMPTY}[1][0.8]{ \begin{tikzpicture}[scale=#1,every node/.style={scale=#1}] \draw (0,0) ellipse (1 and 1); % % % Nr 1 Standard Darstellung ohne Elektronen \draw (0,0) -- (2.5,0); \draw (0,2) -- (2.5,2); \draw (0,3) -- (2.5,3); \draw (0,3.5) -- (2.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (0,3.7) rectangle (2.5,4.2); % % Nr 2 Standard Darstellung ohne Elektronen \draw (4.5,0) -- (7,0); \draw (4.5,2) -- (7,2); \draw (4.5,3) -- (7,3); \draw (4.5,3.5) -- (7,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (4.5,3.7) rectangle (7.0,4.2); % % Pfeile \draw[-triangle 60] (2.7,2) -- (4.3,2); % % Elektronen \filldraw (0.75,0) ellipse (0.1 and 0.1); \filldraw (1.75,0) ellipse (0.1 and 0.1); %\filldraw (-4.5,-3.5) ellipse (0.1 and 0.1); % Elektronenweg % % Beschriftung \node[draw] at (1.25,-1) {A$^{q+}$}; \node[draw] at (5.75,-1) {A$^{(q+1)+}$}; \end{tikzpicture} } %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % Direct Ionization (DI) % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% \newcommand{\atomDI}[1][0.8]{ \begin{tikzpicture}[scale=#1,every node/.style={scale=#1}] % Anker %\draw (0,0) ellipse (1 and 1); % % Nr 1 Standard Darstellung ohne Elektronen \draw (0,0) -- (2.5,0); \draw (0,2) -- (2.5,2); \draw (0,3) -- (2.5,3); \draw (0,3.5) -- (2.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (0,3.7) rectangle (2.5,4.2); % % Nr 2 Standard Darstellung ohne Elektronen \draw (4.5,0) -- (7,0); \draw (4.5,2) -- (7,2); \draw (4.5,3) -- (7,3); \draw (4.5,3.5) -- (7,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (4.5,3.7) rectangle (7.0,4.2); % % Pfeile \draw[-triangle 60] (2.7,2) -- (4.3,2); % % Elektronen (von unten nach oben) \filldraw (0.75,0) ellipse (0.1 and 0.1); \filldraw (1.75,0) ellipse (0.1 and 0.1); \filldraw (1.75,2.0) ellipse (0.1 and 0.1); \filldraw (-1.5,5.5) ellipse (0.1 and 0.1); % Kontinuum Elektron % \filldraw (5.25,0) ellipse (0.1 and 0.1); \filldraw (6.25,0) ellipse (0.1 and 0.1); \filldraw (7.5,4.5) ellipse (0.1 and 0.1); % freie Elektronen \filldraw (7.5,4.0) ellipse (0.1 and 0.1); % % Elektronenweg \draw [-triangle 60](-1.5,5.5) -- (1.75,5.5) -- (1.75,4.5) -- (2.9,4.5); % Kontinuum Elektron \draw [-triangle 60](1.75,2.5) -- (1.75,4.2) -- (2.9,4.2); % \draw [-triangle 60] (7.5,4.5) -- (9,4.5); % freie Elektronen \draw [-triangle 60] (7.5,4.0) -- (9,4.0); % % Beschriftung \node[draw] at (1.25,-1) {A$^{q+}$}; \node[draw] at (5.75,-1) {A$^{(q+1)+}$}; \end{tikzpicture} } % % % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % Excitation auto-ionization (EA) % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% \newcommand{\atomEA}[1][0.8]{ \begin{tikzpicture}[scale=#1,every node/.style={scale=#1}] % Anker % \draw (0,0) ellipse (1 and 1); % % Nr 1 Standard Darstellung ohne Elektronen \draw (0,0) -- (2.5,0); \draw (0,2) -- (2.5,2); \draw (0,3) -- (2.5,3); \draw (0,3.5) -- (2.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (0,3.7) rectangle (2.5,4.2); % % Nr 2 Standard Darstellung ohne Elektronen \draw (4.5,0) -- (7,0); \draw (4.5,2) -- (7,2); \draw (4.5,3) -- (7,3); \draw (4.5,3.5) -- (7,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (4.5,3.7) rectangle (7.0,4.2); % % Nr 3 Standard Darstellung ohne Elektronen \draw (9,0) -- (11.5,0); \draw (9,2) -- (11.5,2); \draw (9,3) -- (11.5,3); \draw (9,3.5) -- (11.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (9.0,3.7) rectangle (11.5,4.2); % % Pfeile \draw[-triangle 60] (2.7,2) -- (4.3,2); % 1 nach 2 \draw[-triangle 60] (7.2,2) -- (8.8,2); % 2 nach 3 % % Elektronen (von unten nach oben) % Nr 1 Standard \filldraw (0.75,0) ellipse (0.1 and 0.1); \filldraw (1.75,0) ellipse (0.1 and 0.1); \filldraw (1.75,2.0) ellipse (0.1 and 0.1); \filldraw (-1.5,5.5) ellipse (0.1 and 0.1); % Kontinuum Elektron % Elektronen (von unten nach oben) % Nr 2 Standard \filldraw (6.25,0) ellipse (0.1 and 0.1); \filldraw (6.25,2) ellipse (0.1 and 0.1); \filldraw (5.25,3) ellipse (0.1 and 0.1); \filldraw (6.6,4.5) ellipse (0.1 and 0.1); % freie Elektronen % Elektronen (von unten nach oben) % Nr 3 Standard \filldraw (9.75,0) ellipse (0.1 and 0.1); \filldraw (10.75,0) ellipse (0.1 and 0.1); \filldraw (12,4.5) ellipse (0.1 and 0.1); % freie Elektronen \filldraw (12,5.3) ellipse (0.1 and 0.1); % abgelöstes Elektron % % Elektronenweg % Nr 1 Standard \draw [-triangle 60](-1.5,5.5) -- (1.25,5.5) -- (1.25,4.5) -- (2.0,4.5); % Kontinuum Elektron \draw [-triangle 60](0.75,0) -- (0.75,3); % Elektronenweg % Nr 2 Standard \draw [-triangle 60](5.25,3) -- (5.25,0); \draw [-triangle 60](6.25,2.0) -- (6.25,5.3) -- (7.1,5.3); % abgelöstes Elektron \draw [-triangle 60](6.6,4.5) -- (7.4,4.5); % freie Elektronen % Elektronenweg % Nr 3 Standard \draw [-triangle 60](12,4.5) -- (13,4.5); % abgelöstes Elektron \draw [-triangle 60](12,5.3) -- (13,5.3); % freie Elektronen % % Beschriftung \node[draw] at (1.25,-1) {A$^{q+}$}; % 1 \node[draw] at (5.75,-1) {[A$^{q+}$]$^*$}; % 2 \node[draw] at (10.25,-1) {A$^{(q+1)+}$}; % 3 \end{tikzpicture} } % % % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % Ionization-auto-ionization (IA) % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% \newcommand{\atomIA}[1][0.8]{ \begin{tikzpicture}[scale=#1,every node/.style={scale=#1}] % Anker %\draw (0,0) ellipse (1 and 1); % % % Nr 1 Standard Darstellung ohne Elektronen \draw (0,0) -- (2.5,0); \draw (0,2) -- (2.5,2); \draw (0,3) -- (2.5,3); \draw (0,3.5) -- (2.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (0,3.7) rectangle (2.5,4.2); % % Nr 2 Standard Darstellung ohne Elektronen \draw (4.5,0) -- (7,0); \draw (4.5,2) -- (7,2); \draw (4.5,3) -- (7,3); \draw (4.5,3.5) -- (7,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (4.5,3.7) rectangle (7.0,4.2); % % Nr 3 Standard Darstellung ohne Elektronen \draw (9,0) -- (11.5,0); \draw (9,2) -- (11.5,2); \draw (9,3) -- (11.5,3); \draw (9,3.5) -- (11.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (9.0,3.7) rectangle (11.5,4.2); % % Pfeile \draw[-triangle 60] (2.7,2) -- (4.3,2); % 1 nach 2 \draw[-triangle 60] (7.2,2) -- (8.8,2); % 2 nach 3 % % Elektronen (von unten nach oben) % Nr 1 Standard \filldraw (0.75,0) ellipse (0.1 and 0.1); \filldraw (1.75,0) ellipse (0.1 and 0.1); \filldraw (1.75,2.0) ellipse (0.1 and 0.1); \filldraw (1.75,3.0) ellipse (0.1 and 0.1); \filldraw (-1.0,7.5) ellipse (0.1 and 0.1); % Kontinuum Elektron % % Elektronen (von unten nach oben) % Nr 2 Standard \filldraw (5.25,0) ellipse (0.1 and 0.1); \filldraw (6.25,2) ellipse (0.1 and 0.1); \filldraw (6.25,3) ellipse (0.1 and 0.1); \filldraw (6.5,4.75) ellipse (0.1 and 0.1); % erstes abgelöstes Elektronen, frei unten \filldraw (6.25,5.1) ellipse (0.1 and 0.1); % freies Elektron oben % % Elektronen (von unten nach oben) % Nr 3 Standard \filldraw (9.75,0) ellipse (0.1 and 0.1); \filldraw (10.75,0) ellipse (0.1 and 0.1); \filldraw (11.8,4.5) ellipse (0.1 and 0.1); % % zweites abgelöstes Elektronen, frei unten \filldraw (12.5,4.75) ellipse (0.1 and 0.1); % erstes abgelöstes Elektronen, frei unten \filldraw (12,5.1) ellipse (0.1 and 0.1); % freies Elektron oben % % % Elektronenweg % Nr 1 Standard \draw [-triangle 60](-1.0,7.5) -- (0.75,7.5) -- (0.75,5.1) -- (2.0,5.1); % Kontinuum Elektron \draw [-triangle 60](0.75,0) -- (0.75,4.75) -- (2.0,4.75); % abgelöstes Elektron % % Elektronenweg % Nr 2 Standard \draw [-triangle 60](6.25,2) -- (6.25,0); \draw [-triangle 60](6.25,3.0) -- (6.25,4.5) -- (7.5,4.5); % zweites abgelöstes Elektron \draw [-triangle 60](6.5,4.75) -- (8,4.75); % erstes abgelöstes Elektron \draw [-triangle 60](6.25,5.1) -- (7.7,5.1); % freie Elektronen % % Elektronenweg % Nr 3 Standard \draw [-triangle 60](11.8,4.5) -- (13.5,4.5) ; % zweites abgelöstes Elektron \draw [-triangle 60](12.5,4.75) -- (14,4.75); % erstes abgelöstes Elektron \draw [-triangle 60](12,5.1) -- (13.7, 5.1); % freie Elektronen % % Beschriftung \node[draw] at (1.25,-1) {A$^{q+}$}; % 1 \node[draw] at (5.75,-1) {[A$^{(q+1)+}$]$^*$}; % 2 \node[draw] at (10.25,-1) {A$^{(q+2)+}$}; % 3 % \end{tikzpicture} } %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % Resonant elastic scattering (RES) % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% \newcommand{\atomRES}[1][0.8]{ \begin{tikzpicture}[scale=#1,every node/.style={scale=#1}] % Anker %\draw (0,0) ellipse (1 and 1); % % Nr 1 Standard Darstellung ohne Elektronen \draw (0,0) -- (2.5,0); \draw (0,2) -- (2.5,2); \draw (0,3) -- (2.5,3); \draw (0,3.5) -- (2.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (0,3.7) rectangle (2.5,4.2); % % Nr 2 Standard Darstellung ohne Elektronen \draw (4.5,0) -- (7,0); \draw (4.5,2) -- (7,2); \draw (4.5,3) -- (7,3); \draw (4.5,3.5) -- (7,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (4.5,3.7) rectangle (7.0,4.2); % % Nr 3 Standard Darstellung ohne Elektronen \draw (9,0) -- (11.5,0); \draw (9,2) -- (11.5,2); \draw (9,3) -- (11.5,3); \draw (9,3.5) -- (11.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (9.0,3.7) rectangle (11.5,4.2); % % % Pfeile zwischen Abbildungen \draw[-triangle 60] (2.7,2) -- (4.3,2); % 1 nach 2 \draw[-triangle 60] (7.2,2) -- (8.8,2); % 2 nach 3 % % % Elektronen (von unten nach oben) % Nr 1 Standard \filldraw (1.75,0) ellipse (0.1 and 0.1); \filldraw (0.75,5.5) ellipse (0.1 and 0.1); % Kontinuum Elektron % Elektronen (von unten nach oben) % % Nr 2 Standard \filldraw (5.25,3.5) ellipse (0.1 and 0.1); % freie Elektronen \filldraw (6.25,3.0) ellipse (0.1 and 0.1); % % Elektronen (von unten nach oben) % Nr 3 Standard \filldraw (10.75,0) ellipse (0.1 and 0.1); \filldraw (10.75,5.5) ellipse (0.1 and 0.1); % erstes abgelöstes Elektronen, frei unten % % % % Elektronenweg % Nr 1 Standard \draw [-triangle 60](0.75,5.5) -- (0.75,3.5); % Kontinuum Elektron \draw [-triangle 60](1.75,0) -- (1.75,3); % % Elektronenweg % Nr 2 Standard \draw [-triangle 60](6.25,3.0) -- (6.25,0); \draw (5.25,3.5) -- (5.25,5.5) ; % erstes abgelöstes Elektron \draw [-triangle 60](5.24,5.5) -- (5.8,5.5) ; % erstes abgelöstes Elektron % % Elektronenweg % Nr 3 Standard \draw [-triangle 60](10.75,5.5) -- (12.0,5.5) ; % erstes abgelöstes Elektron % % % Beschriftung \node[draw] at (1.25,-1) {A$^{q+}$}; % 1 \node[draw] at (5.75,-1) {[A$^{(q-1)+}$]$^{**}$}; % 2 \node[draw] at (10.25,-1) {A$^{q+}$}; % 3 \end{tikzpicture} } %%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % Trielectronic Capture (TC) % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%% \newcommand{\atomTC}[1][0.8]{ \begin{tikzpicture}[scale=#1,every node/.style={scale=#1}] % Anker %\draw (0,0) ellipse (1 and 1); % % Nr 1 Standard Darstellung ohne Elektronen \draw (0,0) -- (2.5,0); \draw (0,2) -- (2.5,2); \draw (0,3) -- (2.5,3); \draw (0,3.5) -- (2.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (0,3.7) rectangle (2.5,4.2); % % Nr 2 Standard Darstellung ohne Elektronen \draw (4.5,0) -- (7,0); \draw (4.5,2) -- (7,2); \draw (4.5,3) -- (7,3); \draw (4.5,3.5) -- (7,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (4.5,3.7) rectangle (7.0,4.2); % % Nr 3 Standard Darstellung ohne Elektronen \draw (9,0) -- (11.5,0); \draw (9,2) -- (11.5,2); \draw (9,3) -- (11.5,3); \draw (9,3.5) -- (11.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (9.0,3.7) rectangle (11.5,4.2); % % % Pfeile zwischen Abbildungen \draw[-triangle 60] (2.7,2) -- (4.3,2); % 1 nach 2 \draw[-triangle 60] (7.2,2) -- (8.8,2); % 2 nach 3 % % % Elektronen (von unten nach oben) % Nr 1 Standard \filldraw (0.75,0) ellipse (0.1 and 0.1); \filldraw (1.75,0) ellipse (0.1 and 0.1); \filldraw (0.75,6) ellipse (0.1 and 0.1); % Kontinuum Elektron % Elektronen (von unten nach oben) % % Nr 2 Standard \filldraw (5.25,3.5) ellipse (0.1 and 0.1); % freie Elektronen \filldraw (6.25,3.0) ellipse (0.1 and 0.1); \filldraw (5.25,2.0) ellipse (0.1 and 0.1); % % Elektronen (von unten nach oben) % Nr 3 Standard \filldraw (9.75,0) ellipse (0.1 and 0.1); \filldraw (11.75,4.0) ellipse (0.1 and 0.1); % erstes abgelöstes Elektronen, frei unten \filldraw (11.9,4.3) ellipse (0.1 and 0.1); % freies Elektron oben % % % % Elektronenweg % Nr 1 Standard \draw (0.75,6) -- (0.75,5.05); % Kontinuum Elektron \draw (0.9,5.1) -- (0.6,5); % Kontinuum Elektron, vertical line \draw (0.9,5.0) -- (0.6,4.9); % Kontinuum Elektron, vertical line \draw [-triangle 60](0.75,4.95) -- (0.75,3.5); % Kontinuum Elektron \draw [-triangle 60](1.75,0) -- (1.75,3); \draw [-triangle 60](0.75,0) -- (0.75,2.0); % 1st Electron in groundstate % % Elektronenweg % Nr 2 Standard \draw [-triangle 60](6.25,3.0) -- (6.25,0); \draw [-triangle 60](5.25,2.0) -- (5.25,0); \draw [line width=0.3mm] (5.25,3.5) -- (5.25,4.0) ; % erstes abgelöstes Elektron \draw [line width=0.3mm,-triangle 60](5.235,4.0) -- (5.8,4) ; % erstes abgelöstes Elektron \draw [line width=0.3mm] (6.25,3.0) -- (6.25,4.5) ; % zweites abgelöstes Elektron \draw [line width=0.3mm,-triangle 60](6.235,4.5) -- (6.8,4.5) ; % zweites abgelöstes Elektron % % Elektronenweg % Nr 3 Standard \draw [-triangle 60](11.75,4.0) -- (12.3,4.0) ; % erstes abgelöstes Elektron \draw [-triangle 60](11.9,4.3) -- (12.5,4.3) ; % zweites abgelöstes Elektron % % % Beschriftung \node[draw] at (1.25,-1) {A$^{q+}$}; % 1 \node[draw] at (5.75,-1) {[A$^{(q-1)+}$]$^{***}$}; % 2 \node[draw] at (10.25,-1) {[A$^{(q-1)+}$]$^{*}$}; % 3 \end{tikzpicture} } %%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%% % Resonant excitation (RE) % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% \newcommand{\atomRE}[1][0.8]{ \begin{tikzpicture}[scale=#1,every node/.style={scale=#1}] % Anker %\draw (0,0) ellipse (1 and 1); % % Nr 1 Standard Darstellung ohne Elektronen \draw (0,0) -- (2.5,0); \draw (0,2) -- (2.5,2); \draw (0,3) -- (2.5,3); \draw (0,3.5) -- (2.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (0,3.7) rectangle (2.5,4.2); % % Nr 2 Standard Darstellung ohne Elektronen \draw (4.5,0) -- (7,0); \draw (4.5,2) -- (7,2); \draw (4.5,3) -- (7,3); \draw (4.5,3.5) -- (7,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (4.5,3.7) rectangle (7.0,4.2); % % Nr 3 Standard Darstellung ohne Elektronen \draw (9,0) -- (11.5,0); \draw (9,2) -- (11.5,2); \draw (9,3) -- (11.5,3); \draw (9,3.5) -- (11.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (9.0,3.7) rectangle (11.5,4.2); % % % Pfeile zwischen Abbildungen \draw[-triangle 60] (2.7,2) -- (4.3,2); % 1 nach 2 \draw[-triangle 60] (7.2,2) -- (8.8,2); % 2 nach 3 % % % Elektronen (von unten nach oben) % Nr 1 Standard \filldraw (1.75,0) ellipse (0.1 and 0.1); \filldraw (0.75,5.5) ellipse (0.1 and 0.1); % Kontinuum Elektron % Elektronen (von unten nach oben) % % Nr 2 Standard \filldraw (5.25,3.5) ellipse (0.1 and 0.1); % freie Elektronen \filldraw (6.25,3.0) ellipse (0.1 and 0.1); % % Elektronen (von unten nach oben) % Nr 3 Standard \filldraw (10.75,2) ellipse (0.1 and 0.1); \filldraw (10.95,4.4) ellipse (0.1 and 0.1); % erstes abgelöstes Elektronen, frei unten % % % % Elektronenweg % Nr 1 Standard \draw [-triangle 60](0.75,5.5) -- (0.75,3.5); % Kontinuum Elektron \draw [-triangle 60](1.75,0) -- (1.75,3); % % Elektronenweg % Nr 2 Standard \draw [-triangle 60](6.25,3.0) -- (6.25,2.0); \draw (5.25,3.5) -- (5.25,4.4) ; % erstes abgelöstes Elektron \draw [-triangle 60](5.242,4.4) -- (5.8,4.4) ; % erstes abgelöstes Elektron % % Elektronenweg % Nr 3 Standard \draw [-triangle 60](10.95,4.4) -- (12.0,4.4) ; % erstes abgelöstes Elektron % % % Beschriftung \node[draw] at (1.25,-1) {A$^{q+}$}; % 1 \node[draw] at (5.75,-1) {[A$^{(q-1)+}$]$^{**}$}; % 2 \node[draw] at (10.25,-1) {[A$^{q+}$]$^{*}$}; % 3 \end{tikzpicture} } % % % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % REDA and READI % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% \NewDocumentCommand{\atomREDA}{O{0.55} O{1.5}}{% \def\atomREDAscale{#1}% \def\atomREDATextSize{#2}% \begin{tikzpicture}[ scale=\atomREDAscale, every node/.style={scale=\atomREDAscale} ] % Anker %\draw (-12.5,4.15) ellipse (1 and 1); % Anker Start %\draw (0,10) ellipse (1 and 1); % Anker REDA %\draw (0,0) ellipse (1 and 1); % Anker READI %%%%%%%%%%%%%%%%%%%%%%%%%-- Beschriftung --%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % Beschriftung %%% Für Start \node[draw] at (-11.25,3.15) {\textbf{A}$^{q+}$}; % 1 % Beschriftung %%% Für REDA \node[draw,scale=\atomREDATextSize] at (1.25,9) {[\textbf{A}$^{(q-1)+}$]$^{**}$}; % 1 \node[draw,scale=\atomREDATextSize] at (5.75,9) {[\textbf{A}$^{q+}$]$^{*}$}; % 2 \node[draw,scale=\atomREDATextSize] at (10.25,9) {\textbf{A}$^{(q+1)+}$}; % 3 \node[draw,scale=\atomREDATextSize] at (-7.5,8.5) {REDA}; % REDA % Beschriftung %%% Für READI \node[draw,scale=\atomREDATextSize] at (1.25,-1) {[\textbf{A}$^{(q-1)+}$]$^{**}$}; % 1 \node[draw,scale=\atomREDATextSize] at (5.75,-1) {\textbf{A}$^{(q+1)+}$}; % 2 \node[draw,scale=\atomREDATextSize] at (-7.5,3.7) {READI}; % READI %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%-- Standard Darstellung --%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%% Start % Nr 1 Standard Darstellung ohne Elektronen %\draw[red] (-12.5,-2.5) --(-12.5,15); % Anker für Mitte y // %\draw[red] (-12.5,6.25) --(12.5,6.25); % Anker für Mitte x // \draw (-10,4.15) -- (-12.5,4.15); \draw (-10,6.15) -- (-12.5,6.15); \draw (-10,7.15) -- (-12.5,7.15); \draw (-10,7.65) -- (-12.5,7.65); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (-10,7.85) rectangle (-12.5,8.35); %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%% Für REDA % Nr 1 Standard Darstellung ohne Elektronen \draw (0,10) -- (2.5,10); \draw (0,12) -- (2.5,12); \draw (0,13) -- (2.5,13); \draw (0,13.5) -- (2.5,13.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (0,13.7) rectangle (2.5,14.2); % Nr 2 Standard Darstellung ohne Elektronen \draw (4.5,10) -- (7,10); \draw (4.5,12) -- (7,12); \draw (4.5,13) -- (7,13); \draw (4.5,13.5) -- (7,13.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (4.5,13.7) rectangle (7.0,14.2); % Nr 3 Standard Darstellung ohne Elektronen \draw (9,10) -- (11.5,10); \draw (9,12) -- (11.5,12); \draw (9,13) -- (11.5,13); \draw (9,13.5) -- (11.5,13.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (9.0,13.7) rectangle (11.5,14.2); %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%% Für READI % Nr 1 Standard Darstellung ohne Elektronen \draw (0,0) -- (2.5,0); \draw (0,2) -- (2.5,2); \draw (0,3) -- (2.5,3); \draw (0,3.5) -- (2.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (0,3.7) rectangle (2.5,4.2); % Nr 2 Standard Darstellung ohne Elektronen \draw (4.5,0) -- (7,0); \draw (4.5,2) -- (7,2); \draw (4.5,3) -- (7,3); \draw (4.5,3.5) -- (7,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (4.5,3.7) rectangle (7.0,4.2); %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%-- Pfeile --%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%% Für Start % Pfeile \draw[-triangle 60] (-8,6.15) -- (-3,10); % nach REDA \draw[-triangle 60] (-8,6.15) -- (-3,2); % nach READI %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%% Für REDA % Pfeile \draw[-triangle 60] (2.7,12) -- (4.3,12); % 1 nach 2 \draw[-triangle 60] (7.2,12) -- (8.8,12); % 2 nach 3 %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%% Für READI % Pfeile \draw[-triangle 60] (2.7,2) -- (4.3,2); % 1 nach 2 %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%-- Elektronen --%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%% Für Start % Elektronen (von unten nach oben) % Nr 1 Standard \filldraw (-10.75,4.15) ellipse (0.1 and 0.1); \filldraw (-11.25,6.15) ellipse (0.1 and 0.1); \filldraw (-14,10.5) ellipse (0.1 and 0.1); %Kontinuum Elektron %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%% Für REDA % Elektronen (von unten nach oben) % Nr 1 Standard \filldraw (1.25,12.0) ellipse (0.1 and 0.1); \filldraw (1.75,13.0) ellipse (0.1 and 0.1); \filldraw (0.75,13.5) ellipse (0.1 and 0.1); % erstes abgelöstes Elektronen % Elektronen (von unten nach oben) % Nr 2 Standard \filldraw (6.25,12.0) ellipse (0.1 and 0.1); \filldraw (5.75,12.0) ellipse (0.1 and 0.1); \filldraw (6.9,14.6) ellipse (0.1 and 0.1); % erstes abgelöstes Elektronen, frei % Elektronen (von unten nach oben) % Nr 3 Standard \filldraw (10.25,10.0) ellipse (0.1 and 0.1); \filldraw (11.55,14.2) ellipse (0.1 and 0.1); % zweites abgelöstes Elektronen, unten \filldraw (11.75,14.6) ellipse (0.1 and 0.1); % erstes abgelöstes Elektronen, oben %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%% Für READI % Elektronen (von unten nach oben) % Nr 1 Standard \filldraw (1.25,2.0) ellipse (0.1 and 0.1); % ablösendes Elektron \filldraw (1.75,3) ellipse (0.1 and 0.1); % ablösendes Elektron \filldraw (0.75,3.5) ellipse (0.1 and 0.1); % fallendes Elektron % Elektronen (von unten nach oben) % Nr 2 Standard \filldraw (5.25,0) ellipse (0.1 and 0.1); % gefallendes Elektron \filldraw (7.0,4.0) ellipse (0.1 and 0.1); % abgelöstes Elektronen, frei unten \filldraw (6.5,4.3) ellipse (0.1 and 0.1); % abgelöstes Elektronen, frei oben %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%-- Elektronen Weg --%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%% Für Start % Elektronenweg % Nr 1 Standard \draw [-triangle 60](-14,10.5) -- (-12,10.5) -- (-12,7.65); %Kontinuum Elektron \draw [-triangle 60](-10.75,4.15) -- (-10.75,7.15); %angeregtes Elektron %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%% Für REDA % Elektronenweg % Nr 1 Standard \draw [-triangle 60](1.75,13) -- (1.75,12); % gefallendes Elektron \draw [-triangle 60](0.75,13.5) -- (0.75,14.3) -- (1.75,14.3); % abgelöstes Elektron % Nr 2 Standard \draw [-triangle 60](5.75,12) -- (5.75,10); % gefallendes Elektron \draw [-triangle 60](6.25,12) -- (6.25,14.2) -- (7.4,14.2); % ablösendes Elektron \draw [-triangle 60](6.9,14.6) -- (7.90,14.6); % abgelöstes Elektron % Nr 3 Standard \draw [-triangle 60](11.55,14.2) -- (12.5,14.2); % ablösendes Elektron \draw [-triangle 60] (11.75,14.6) -- (12.75,14.6); % abgelöstes Elektron %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%% Für READI % Elektronenweg % Nr 1 Standard \draw [-triangle 60](1.75,3) -- (1.75,4.0) -- (3,4.0); % ablösendes Elektron unten \draw [-triangle 60](1.25,2) -- (1.25,4.3) -- (2.5,4.3); % ablösendes Elektron oben \draw [-triangle 60](0.75,3.5) -- (0.75,0); % fallendes Elektron % Nr 2 Standard \draw [-triangle 60](7,4) -- (8.5,4.0); % ablösendes Elektron unten \draw [-triangle 60](6.5,4.3) -- (8,4.3); % ablösendes Elektron oben \end{tikzpicture} } %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % Dielectronic Recombination (DR) % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% \newcommand{\atomDR}[1][0.8]{ \begin{tikzpicture}[scale=#1,every node/.style={scale=#1}] % Anker %%\draw (0,0) ellipse (1 and 1); % % Nr 1 Standard Darstellung ohne Elektronen \draw (0,0) -- (2.5,0); \draw (0,2) -- (2.5,2); \draw (0,3) -- (2.5,3); \draw (0,3.5) -- (2.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (0,3.7) rectangle (2.5,4.2); % % Nr 2 Standard Darstellung ohne Elektronen \draw (4.5,0) -- (7,0); \draw (4.5,2) -- (7,2); \draw (4.5,3) -- (7,3); \draw (4.5,3.5) -- (7,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (4.5,3.7) rectangle (7.0,4.2); % % Nr 3 Standard Darstellung ohne Elektronen \draw (9,0) -- (11.5,0); \draw (9,2) -- (11.5,2); \draw (9,3) -- (11.5,3); \draw (9,3.5) -- (11.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (9.0,3.7) rectangle (11.5,4.2); % % % Pfeile zwischen Abbildungen \draw[-triangle 60] (2.7,2) -- (4.3,2); % 1 nach 2 \draw[-triangle 60] (7.2,2) -- (8.8,2); % 2 nach 3 % % % Elektronen (von unten nach oben) % Nr 1 Standard \filldraw (1.75,0) ellipse (0.1 and 0.1); \filldraw (0.75,5.5) ellipse (0.1 and 0.1); % Kontinuum Elektron % Elektronen (von unten nach oben) % % Nr 2 Standard \filldraw (5.25,3.5) ellipse (0.1 and 0.1); % freie Elektronen \filldraw (6.25,3.0) ellipse (0.1 and 0.1); % % Elektronen (von unten nach oben) % Nr 3 Standard \filldraw (9.75,3.5) ellipse (0.1 and 0.1); \filldraw (10.75,0) ellipse (0.1 and 0.1); % % % % Elektronenweg % Nr 1 Standard \draw [-triangle 60](0.75,5.5) -- (0.75,3.5); % Kontinuum Elektron \draw [-triangle 60](1.75,0) -- (1.75,3); % % Elektronenweg % Nr 2 Standard \draw [-triangle 60](6.25,3) -- (6.25,0); % % Photonenweg \draw [dotted,-triangle 60](6.4,2.2) -- (7.5,2.8); % frei werdenes Photon \node at (7.4,3.0) {h$\nu$}; % 1 % % Beschriftung \node[draw] at (1.25,-1) {A$^{q+}$}; % 1 \node[draw] at (5.75,-1) {[A$^{(q-1)+}$]$^{**}$}; % 2 \node[draw] at (10.25,-1) {[A$^{(q-1)+}$]$^{*}$}; % 3 \end{tikzpicture} } %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % Trilectronic Recombination (TR) % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% \newcommand{\atomTR}[1][0.8]{ \begin{tikzpicture}[scale=#1,every node/.style={scale=#1}] % Anker %\draw (0,0) ellipse (1 and 1); % % Nr 1 Standard Darstellung ohne Elektronen \draw (0,0) -- (2.5,0); \draw (0,2) -- (2.5,2); \draw (0,3) -- (2.5,3); \draw (0,3.5) -- (2.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (0,3.7) rectangle (2.5,4.2); % % Nr 2 Standard Darstellung ohne Elektronen \draw (4.5,0) -- (7,0); \draw (4.5,2) -- (7,2); \draw (4.5,3) -- (7,3); \draw (4.5,3.5) -- (7,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (4.5,3.7) rectangle (7.0,4.2); % % Nr 3 Standard Darstellung ohne Elektronen \draw (9,0) -- (11.5,0); \draw (9,2) -- (11.5,2); \draw (9,3) -- (11.5,3); \draw (9,3.5) -- (11.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (9.0,3.7) rectangle (11.5,4.2); % % % Pfeile zwischen Abbildungen \draw[-triangle 60] (2.7,2) -- (4.3,2); % 1 nach 2 \draw[-triangle 60] (7.2,2) -- (8.8,2); % 2 nach 3 % % % Elektronen (von unten nach oben) % Nr 1 Standard \filldraw (0.75,0) ellipse (0.1 and 0.1); \filldraw (1.75,0) ellipse (0.1 and 0.1); \filldraw (0.75,6) ellipse (0.1 and 0.1); % Kontinuum Elektron % Elektronen (von unten nach oben) % % Nr 2 Standard \filldraw (5.25,3.5) ellipse (0.1 and 0.1); % freie Elektronen \filldraw (6.25,3.0) ellipse (0.1 and 0.1); \filldraw (5.25,2.0) ellipse (0.1 and 0.1); % % Elektronen (von unten nach oben) % Nr 3 Standard \filldraw (9.75,3.5) ellipse (0.1 and 0.1); \filldraw (9.75,0) ellipse (0.1 and 0.1); \filldraw (10.75,0) ellipse (0.1 and 0.1); % % % % Elektronenweg % Nr 1 Standard \draw (0.75,6) -- (0.75,5.05); % Kontinuum Elektron \draw (0.9,5.1) -- (0.6,5); % Kontinuum Elektron, vertical line \draw (0.9,5.0) -- (0.6,4.9); % Kontinuum Elektron, vertical line \draw [-triangle 60](0.75,4.95) -- (0.75,3.5); % Kontinuum Elektron \draw [-triangle 60](1.75,0) -- (1.75,3); \draw [-triangle 60](0.75,0) -- (0.75,2.0); % 1st Electron in groundstate % % Elektronenweg % Nr 2 Standard \draw [-triangle 60](6.25,3.0) -- (6.25,0); \draw [-triangle 60](5.25,2.0) -- (5.25,0); % % Photonenweg \draw [dotted,-triangle 60](6.4,2.2) -- (7.5,2.8); % frei werdenes Photon \node at (7.4,3.0) {h$\nu_1$}; % 1 % \draw [dotted,-triangle 60](5.4,1.0) -- (7.5,1.3); % frei werdenes Photon \node at (7.4,1.5) {h$\nu_2$}; % 1 % % Beschriftung \node[draw] at (1.25,-1) {A$^{q+}$}; % 1 \node[draw] at (5.75,-1) {[A$^{(q-1)+}$]$^{**}$}; % 2 \node[draw] at (10.25,-1) {[A$^{(q-1)+}$]$^{*}$}; % 3 \end{tikzpicture} } %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % Inner-shell electron removal and subsequent autoionisation via Auger (ISHAU) % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% \newcommand{\atomISHAU}[1][0.8]{ \begin{tikzpicture}[scale=#1,every node/.style={scale=#1}] % Anker %\draw (0,0) ellipse (1 and 1); % % Nr 1 Standard Darstellung ohne Elektronen \draw (0,0) -- (2.5,0); \draw (0,2) -- (2.5,2); \draw (0,3) -- (2.5,3); \draw (0,3.5) -- (2.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (0,3.7) rectangle (2.5,4.2); % % Nr 2 Standard Darstellung ohne Elektronen \draw (4.5,0) -- (7,0); \draw (4.5,2) -- (7,2); \draw (4.5,3) -- (7,3); \draw (4.5,3.5) -- (7,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (4.5,3.7) rectangle (7.0,4.2); % % Nr 3 Standard Darstellung ohne Elektronen \draw (9,0) -- (11.5,0); \draw (9,2) -- (11.5,2); \draw (9,3) -- (11.5,3); \draw (9,3.5) -- (11.5,3.5); \shadedraw [draw=white,top color=lightgray!5,bottom color=darkgray] (9.0,3.7) rectangle (11.5,4.2); % % % Pfeile zwischen Abbildungen \draw[-triangle 60] (2.7,2) -- (4.3,2); % 1 nach 2 \draw[-triangle 60] (7.2,2) -- (8.8,2); % 2 nach 3 % % % Elektronen (von unten nach oben) % Nr 1 Standard \filldraw (1.75,0) ellipse (0.1 and 0.1); \filldraw (-0.8,7.0) ellipse (0.1 and 0.1); % Kontinuum Elektron \filldraw (0.75,0) ellipse (0.1 and 0.1); \filldraw (1.75,2.0) ellipse (0.1 and 0.1); \filldraw (1.75,3.0) ellipse (0.1 and 0.1); % Elektronen (von unten nach oben) % % Nr 2 Standard \filldraw (7.4,4.8) ellipse (0.1 and 0.1); % freie Elektronen \filldraw (7.1,4.5) ellipse (0.1 and 0.1); \filldraw (6.25,3.0) ellipse (0.1 and 0.1); \filldraw (6.25,2.0) ellipse (0.1 and 0.1); \filldraw (5.25,0) ellipse (0.1 and 0.1); % % Elektronen (von unten nach oben) % Nr 3 Standard \filldraw (12.5,4.8) ellipse (0.1 and 0.1); % freie Elektronen \filldraw (12.2,4.5) ellipse (0.1 and 0.1); \filldraw (11.5,5) ellipse (0.1 and 0.1); \filldraw (10.75,0.0) ellipse (0.1 and 0.1); \filldraw (9.75,0) ellipse (0.1 and 0.1); % % % % Elektronenweg % Nr 1 Standard \draw [-triangle 60](-0.8,7.0) -- (0.75,7) -- (0.75,4.8) -- (2.8,4.8); % Kontinuum Elektron \draw [-triangle 60](0.75,0) -- (0.75,4.5) -- (2.8,4.5); % % Elektronenweg % Nr 2 Standard \draw [-triangle 60](6.25,2.0) -- (6.25,0.0); \draw [-triangle 60](6.25,3.0) -- (6.25,5) -- (6.8,5); % erstes abgelöstes Elektron \draw [-triangle 60](7.4,4.8) -- (8.0,4.8); \draw [-triangle 60](7.1,4.5) -- (7.7,4.5); % % Elektronenweg % Nr 3 Standard \draw [-triangle 60](11.5,5.0) -- (12.1,5.0); \draw [-triangle 60](12.5,4.8) -- (13.1,4.8); % erstes abgelöstes Elektron \draw [-triangle 60](12.2,4.5) -- (12.8,4.5); % % % Beschriftung \node[draw] at (1.25,-1) {A$^{q+}$}; % 1 \node[draw] at (5.75,-1) {[A$^{(q+1)+}$]$^{*}$}; % 2 \node[draw] at (10.25,-1) {A$^{(q+2)+}$}; % 3 \end{tikzpicture} } % % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % Bohrmodel with charge and shell % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % Main command: % #1 = Element % #2 = Charge (integer: negative, zero, positive) % #3 = comma-separated shell populations % \NewDocumentCommand{\bohrModel}{mmm}{% \begin{tikzpicture}[scale=1] % Parameters \def\radiusstep{0.8} \def\esize{2pt} % Loop over shells \foreach \electrons [count=\n] in {#3} { \pgfmathsetmacro{\r}{\n * \radiusstep} % Draw shell \draw[gray!60] (0,0) circle (\r); % Draw electrons \foreach \i in {1,...,\electrons} { \pgfmathsetmacro{\angle}{360/\electrons * (\i-1)} \fill ({\r*cos(\angle)}, {\r*sin(\angle)}) circle (\esize); } } % Charge formatting \ifnum#2=0 \node at (0,0) {\Large #1}; \else \ifnum#2>0 \node at (0,0) {\Large $#1^{#2+}$}; \else \pgfmathtruncatemacro{\abscharge}{abs(#2)} \node at (0,0) {\Large $#1^{\abscharge-}$}; \fi \fi \end{tikzpicture} } % % % % \endinput % This is the end of apreax.sty %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% Version history 2025/12/22 - initial start 2026/05/01 - first version